Rheology of carboxymethyl cellulose solutions treated with cellulases
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چکیده
منابع مشابه
Rheology of Carboxymethyl Cellulose Solutions Treated with Cellulases
The effect of cellulase treatments on the rheology of carboxymethyl cellulose (CMC) solutions was studied using a rotational viscometer. The rheological behaviors of CMC solutions of different molecular mass and degrees of substitution where studied as a function of time after various treatments. These solutions were subjected to active and heatdenatured cellulase, a cationic polyelectrolyte (C...
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We report a small angle neutron scattering (SANS) and rheology study of cellulose derivative polyelectrolyte sodium carboxymethyl cellulose with a degree of substitution of 1.2. Using SANS, we establish that this polymer is molecularly dissolved in water with a locally stiff conformation with a stretching parameter[Formula: see text]. We determine the cross sectional radius of the chain ([Formu...
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Various cellulose-ionic liquid solutions were measured with a rotational plate-andplate rheometer and a Capillary Break-up Extensional Rheometer (CaBER). Comparison of the shear and extensional rheological properties showed good agreement in some cases. The CaBER, however, seems to be more sensitive to small variations in solute composition. INTRODUCTION Since almost a decade now, nonderivatizi...
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In this study, we characterize the shear and extensional rheology of dilute to semidilute solutions of cellulose in the ionic liquid 1-ethyl-3-methylimidazolium acetate (EMIAc). In steady shear flow, the semidilute solutions exhibit shear thinning, and the high-frequency complex modulus measured in small amplitude oscillatory shear flow exhibits the characteristic scaling expected for solutions...
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Carboxymethyl cellulose [C6H7O(OH)3x(OCH2COOH)x]n is a derivative of the regenerated cellulose [C6H10O5]n with hydroxy-acetic acid (hydroxy ethanoic acid) CH2(OH)COOH or sodium monochloroacetate ClCH2COONa. The CMC backbone consist of D-glucose residues linked by -1,4-linkage. The molecular mass of one glucose unit in CMC chain is mCMC = 146.14 + 75.04x, where x 3 is the degree of substitu...
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ژورنال
عنوان ژورنال: BioResources
سال: 2007
ISSN: 1930-2126,1930-2126
DOI: 10.15376/biores.2.1.20-33